Nano-stiltskin: Turning gold into … see-through rubber

Solar panels, we all know in time this industry has to be huge as we battle climate change and need new sustainable sources of energy. Turning gold into … see-through rubber. Flexible solar panels would benefit from stretchable, damage-resistant, transparent metal electrodes. Researchers found that topology and the adhesion between a metal nanomesh and the underlying substrate played key roles in creating such materials.

Flexible solar panels that could be rolled up for easy transport and other devices would benefit from transparent metal electrodes that can conduct electricity, are stretchable, and resist damage following repeated stretching. Researchers found that topology and the adhesion between a metal nanomesh and the underlying substrate played key roles in creating such materials. The metal nanomesh can be stretched to three times its length while maintaining a transparency comparable to similar commercial materials used in solar cells and flat panel displays. Also, nanomeshes on pre-stretched slippery substrates led to electrodes that didn’t wear out, even after being stretched 50,000 times.

Super stretchable, transparent metal nanomeshes are ideal electrodes for flexible electronics and pacemaker electrodes in implants.

Next-generation flexible electronics require highly stretchable and transparent electrodes. Fatigue, structural damage due to repeated use, is deadly in metals as it leads to poor conductivity and it commonly occurs in metals with repeated stretching — even with short elongations. However, few electronic conductors are transparent and stretchable, even fewer can be cyclically stretched to a large strain without causing fatigue. Now researchers led by the University of Houston found that optimizing topology of a metal nanomesh and its adhesion to an underlying substrate improved stretchability and eliminated fatigue, while maintaining transparency.

A special lithographic technique called «grain boundary lithography» controlled the dimensions of the mesh structure. The metal nanomesh remained transparent after being stretched to three times its length. Gold nanomeshes on prestretched slippery substrates impressively showed no wear when stretched 50,000 times. The slippery surface advantageously allowed the structure of the nanomesh to reorient to relax the stress. Such electrically conductive, flexible, and transparent electrodes could lead to next-generation flexible electronics such as advanced solar cells. The nanomesh electrodes are also promising for implantable electronics because the nanomeshes are biocompatible.

This work was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences (University of Houston); the National Science Foundation (Harvard University); National Institutes of Health (cell cultures for biocompatibility assessments); US Air Force Office of Scientific Research; T. L. L. Temple Foundation; John J. and Rebecca Moores Endowment; State of Texas; and National Natural Science Foundation of China.

Story Source:

The above post is reprinted from materials provided by Department of Energy, Office of Science. Note: Content may be edited for style and length.

Journal Reference:

Chuan Fei Guo, Qihan Liu, Guohui Wang, Yecheng Wang, Zhengzheng Shi, Zhigang Suo, Ching-Wu Chu, Zhifeng Ren. Fatigue-free, superstretchable, transparent, and biocompatible metal electrodes. Proceedings of the National Academy of Sciences, 2015; 112 (40): 12332 DOI: 10.1073/pnas.1516873112